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Nd:YVO4

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我司的Nd:YVO4晶體產(chǎn)品,又稱摻釹釩酸釔晶體。是一種綜合性能出色的制作半導(dǎo)體泵浦固體激光器的激光晶體產(chǎn)品。Nd:YVO4晶體廣泛用于在機(jī)械、材料加工、波譜學(xué)、晶片檢驗(yàn)、顯示器、醫(yī)學(xué)檢測、激光印刷、數(shù)據(jù)存儲(chǔ)等多個(gè)領(lǐng)域。該產(chǎn)品有熱導(dǎo)性能好,受激發(fā)射截面大,激光損傷閾值高、吸收帶寬,吸收峰約808nm等特點(diǎn)。由于這些優(yōu)點(diǎn),小晶體可以用來制造更小的激光器件。Nd:YVO4晶體的另一個(gè)特點(diǎn)是它是單軸的,這使得它發(fā)出線性偏振光。與倍頻晶體相結(jié)合,可以實(shí)現(xiàn)綠、藍(lán)、紅三種波長的全固態(tài)激光器?,F(xiàn)在Nd:YVO4激光器已在機(jī)械、材料加工、波譜學(xué)、晶片檢驗(yàn)、顯示器、醫(yī)學(xué)檢測、激光印刷、數(shù)據(jù)存儲(chǔ)等多個(gè)領(lǐng)域得到廣泛的應(yīng)用。而且Nd:YVO4二極管泵浦固態(tài)激光器正在迅速取代傳統(tǒng)的水冷離子激光器和燈泵浦激光器的市場,尤其是在小型化和單縱模輸出方面??梢赃\(yùn)用在激光二極管泵浦全固態(tài)(DPSS)微小型激光器,激光雷達(dá),遙感衛(wèi)星產(chǎn)品之中。

特點(diǎn)

  • 吸收系數(shù)高
  • 受激發(fā)射截面大
  • 吸收帶寬
  • 損傷閾值高
  • 單軸晶體
  • 良好的物理和光學(xué)性能

材料規(guī)格

材料Nd: YVO4
濃度公差(atm%)0.5%, 1.1%, 2.0%, 3.0%
取向A-cut or C-cut
平行性20〞
垂直性5〞
表面質(zhì)量符合MIL-O-13830 B10/5劃痕/凹陷
波前畸變<λ/8 @633nm
表面平整度λ/10@ 633 nm
通光孔徑>90%
倒角≤0.2mm@450
尺寸公差(W±0.1mm)x(H±0.1mm)x(L+0.2/-0.1mm) (L<2.5mm)
(W±0.1mm)x(H±0.1mm)x(L+0.5/-0.1mm) (L≥2.5mm)
角度公差≤0.5°
損傷閾值[GW / cm2]>1 for 1064nm, TEM00, 10ns, 10Hz (AR-涂層)
涂層HR@1064nm+532nm+HT@808nm/AR@1064nm+532nm

物理和化學(xué)特性

晶體結(jié)構(gòu)鋯石四方體,空間群D4h-I4 / amd
晶格常數(shù)a=b=7.12, c=6.29
密度4.22g/cm3
熔點(diǎn)1825
導(dǎo)熱系數(shù)/(W·m-1·K-1 @ 25°C)5.2
熱光學(xué)系數(shù)(dn / dT)dno/dT=8.5×10-6/K; dne/dT=2.9×10-6/K
熱膨脹率/(10-6·K-1 @ 25°C)a = 4.43, c= 11.4
硬度(莫氏)4~5

光學(xué)和光譜性質(zhì)

激光波長1064nm, 1342nm
偏振激光發(fā)射π偏振;平行于光軸(c軸)
泵浦波長808nm
本征損失0.02cm-1?@1064nm
二極管泵浦光到光效率>60%
發(fā)射截面25×10-19cm2@1064nm
熒光壽命90 μs (大約 50 μs for 2 atm% Nd 摻雜) @ 808 nm
增益帶寬0.96nm @1064nm
折光率1.9573(no); 2.1652(ne) @1064nm
1.9721(no); 2.1858(ne) @808nm
2.0210(no); 2.2560(ne) @532nm
吸收系數(shù)31.4 cm-1?@ 808 nm
吸收長度0.32 mm @ 808 nm
增益帶寬0.96 nm (257 GHz) @ 1064 nm

吸收和發(fā)射光譜

Nd-YVO4激光晶體-吸收譜1-南京光寶-CRYLINKNd-YVO4激光晶體-吸收譜2-南京光寶-CRYLINK
Nd-YVO4激光晶體-發(fā)射譜π-南京光寶-CRYLINKNd-YVO4激光晶體-發(fā)射譜σ-南京光寶-CRYLINK

參考文獻(xiàn)

[1]? Hong Z ,? Yang H ,? Zhang Y , et al. Nd:YVO 4 crystal growth by the floating zone method[J]. Journal of Crystal Growth, 1996, 160(1-2):136-140.
[2] Dal, Hoy, Kwon, et al. Growth of Nd-doped YVO4 single crystals along 〈1?0?0〉tetra by the anisotropic heating floating zone method[J]. Journal of Crystal Growth, 2009.
[3]? Lin H Y ,? Copner N ,? Sun D , et al. Dual-wavelength CW a-cut Nd:YVO4 laser at 1064.3 and 1066.7nm[J]. OPTIK -STUTTGART-, 2016.
[4]? Lin H Y ,? Sun D ,? Huang X H , et al. Continuous-wave dual-wavelength Nd:YVO4 laser at 1066.4nm and 1083.8nm[J]. Optik – International Journal for Light and Electron Optics, 2016, 127(11):4824-4825.
[5]? Zhuang Z ,? Tao L ,? Li X , et al. Investigation of Nd:YVO4/YVO4 composite crystal and its laser performance pumped by a fiber coupled diode laser[J]. Optics Communications, 2007, 274(1):176-181.
[6] H.F. Lin and W.Z. Zhu and F.B. Xiong and R.Z. Mu and Y.Q. Huang. A high polarization microchip green laser with dual Nd:YVO4 crystal[J]. Optics & Laser Technology, 2012.
[7]? Zhang H ,? Liu J ,? Wang J , et al. Laser properties of different Nd-doped concentration Nd:YVO 4 laser crystals[J]. Optics & Lasers in Engineering, 2002, 38(6):527-536.
[8]? Li S ,? Li Y ,? Zhao S , et al. Thermal effect investigation and passively Q-switched laser performance of composite Nd:YVO4 crystals[J]. Optics & Laser Technology, 2015, 68:146-150.
[9]? Sugiyama A ,? Nara Y . Improved direct bonding method of Nd:YVO and YVO laser crystals[J]. Ceramics International, 2005, 31(8):1085-1090.
[10]? Meng X ,? Li Z ,? Zhang H . Growth, morphology and laser performance of Nd:YVO4 crystal[J]. Journal of Crystal Growth, 1999, 200(1/2):199-203.
[11]? Zhang H ,? Meng X ,? Li Z , et al. Growth, spectra and influence of annealing effect on laser properties of Nd:YVO 4 crystal[J]. Optical Materials, 2000, 14(1):25-30.
[12]? Lian Z ,? Peng L ,? Liu T , et al. Optical properties of planar waveguide in Nd:YVO4 crystal formed by swift Kr8+ ion irradiation[J]. Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms, 2013, 307(8):459-462.
[13]? Ma Y J , F Lu,? Yin J J , et al. Radiation damage study of MeV ions-implanted Nd:YVO4 crystal[J]. Materials Science and Engineering: B, 2013, 178(20):1464-1468.
[14] Alfred, R, Forbes, et al. The hydrothermal synthesis, solubility and crystal growth of YVO4 and Nd:YVO4[J]. Journal of Crystal Growth, 2008, 310(20):4472-4476.
[15]? Wang Z ,? Sun L ,? Zhang S , et al. Investigation of LD end-pumped Nd:YVO 4 crystals with various doping levels and lengths[J]. Optics & Laser Technology, 2001, 33(1):47-51.
[16]? G. V , Vázquez, and, et al. Analysis of ion implanted waveguides formed on Nd:YVO4 crystals – ScienceDirect[J]. Optics Communications, 2004, 240(4-6):351-355.
[17]? Huang C H ,? Chen J C . Nd : YVO4 single crystal fiber growth by the LHPG method[J]. Journal of Crystal Growth, 2001, 229:184–187.
[18]? Zhang H ,? Fang H S ,? Zheng L L , et al. Nd:YVO4 crystal growth by Czochralski technique with a submerged plate[J]. Journal of Crystal Growth, 2009, 311(22):4652-4659.
[19]? Shur J W ,? Kochurikhin V V ,? Borisova A E , et al. Photoluminescence properties of Nd:YVO 4 single crystals by multi-die EFG method[J]. Optical Materials, 2004, 26(4):347-350.
[20] S. Erdei and B.M. Jin and F.W. Ainger and B. Keszei and J. Vandlik and A. Süveges. Possible trends for the growth of low scattering Nd:YVO4 laser crystals; phase relations — growth techniques[J]. Journal of Crystal Growth, 1997.
[21]? Hu B Q ,? Zhang Y Z ,? Wu X , et al. Defects in large single crystals Nd : YVO 4[J]. Journal of Crystal Growth, 2001, 226(4):511-516.
[22]? Goutaudier C ,? Ermeneux F S ,? Cohen-Adad M T , et al. LHPG and FLUX growth of various Nd:YVO4 single crystals: A comparative characterization[J]. Materials Research Bulletin, 1998, 33(10):1457-1465.
[23] Hur,? M. G , Yang, et al. Optical properties of EFG grown Nd:YVO4 single crystals dependent on Nd concentration.[J]. Journal of Crystal Growth, 2002.
[24]? Nakamura K ,? Kasahara K ,? Sato M , et al. Interferometric studies on a diode-pumped Nd:YVO 4 laser with frequency-shifted feedback[J]. Optics Communications, 1995, 121(4-6):137-140.
[25]? Helen Y ,? Dassow R ,? Nerding M , et al. High mobility thin film transistors by Nd:YVO4-laser crystallization[J]. Thin Solid Films, 2001, 383(1-2):143-146.
[26]? Watanabe S ,? Nakamura O ,? Kochurikhin V V , et al. Growth of Nd:YVO 4 single-crystal plates by the edge-defined, film-fed growth technique[J]. Journal of Crystal Growth, 2007, 305(1):181-184.
[27] MD Wei,? Hsu C C . Numerical study of nonlinear dynamics in a pump-modulation Nd:YVO4 laser with humped modulation profile[J]. Optics Communications, 2012, 285(6):1366-1370.
[28]? Chen Y ,? Wu E ,? Zhang S , et al. A novel ring laser resonator of linear geometry with twin off-axially cut Nd:YVO4[J]. Optics Communications, 2003, 220(1-3):179-186.

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