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Yb:KGW

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Yb:KGW

Yb3+:KGd(WO42(Yb:KGW)是最有前途的激光活性材料之一。Yb:KGW晶體有望取代Nd:YAG晶體和Yb:YAG晶體應用于大功率二極管泵浦激光系統。Yb:KGW在高功率、短脈沖飛秒激光及其廣泛應用方面也具有巨大的潛力。

Yb3KGW具有大的吸收系數,低的量子缺陷,高的吸收和發射截面

Yb離子簡單的二能級電子結構避免了上轉換、激發態吸收和濃度猝滅等非期望的損耗過程。與常用的Nd:YAG晶體相比,Yb:KGW晶體具有更大的吸收帶寬、3-4倍的發射壽命、更高的存儲容量、更低的量子缺陷,更適合于二極管泵浦。斯托克斯位移越小,加熱越小,激光效率越高。與Yb:YAG和Yb:YCOB等摻Yb激光晶體相比,Yb:KGW具有更高的吸收截面(13-17倍)、更低的量子缺陷(~4%)、比Yb:YCOB高9倍的發射截面和比Yb:YAG寬的發射帶、高的非線性折射系數和斜率效率最高(87%)。

  • 吸收線寬度寬,無需嚴格的溫度控制即可獲得相位匹配的LD泵浦源的泵浦波長;
  • 量子缺陷低,泵浦波長非常接近激光輸出波長,導致固有的激光斜率效率高,理論上量子效率可達90%左右;
  • 由于泵浦的能級接近激光的上限,因此沒有輻射弛豫的材料中的熱負荷很低,僅是摻釹釹激光材料的熱負荷的三分之一;
  • 無激發態吸收和上轉換,光轉換效率高;
  • 熒光壽命長,是相同的摻釹激光材料的三倍以上,有利于能量存儲;

物理和化學特性

化學式Yb3+KGdWO42
晶體結構單斜雙鎢酸鹽
密度7.27 g/cm3
傳輸范圍0.35-5.5 μm
莫氏硬度4 to 5
1060 nm的折射率ng?= 2.037, np?= 1.986, nm=2.033

光學和熱學特性

導熱系數Ka=2.6 W/mK, Kb=3.8 W/mK, Kc=3.4 W/mK
熱光學系數@ 1064 nmdnp/dT=-15.7 * 10-6?K-1
dnm/dT=-11.8 * 10-6?K-1
dng/dT=-17.3 * 10-6?K-1
熱膨脹αa=4X10-6?/°C
αb=3.6X10-6?/°C
αc=8.5X10-6?/°C
熔點溫度1075?°C
吸收截面1.2X10-19?cm2
受激發射橫截面(E || a)2.6X10-20?cm2
激光波長1023-1060 nm
激光閾值35 mW
Yb3 +的2F5/2歧管在77 K時的純能級(cm-1)10682, 10471, 10188
在77K時,Yb3 +的2F7/2流形的斯塔克能級(以cm-1為單位)535, 385, 163, 0
光學損傷閾值,GW / cm220

光譜性質

吸收峰波長,lpump,[nm]981.2
吸收線寬,Dlpump,[nm]3.7
峰吸收橫截面,冒泡,[cm2]1.2×10-19
峰值吸收系數,[cm-1]26
發射波長,lse,[nm]1023
發射線寬,Dlse,[nm]20
峰值發射截面,sse,[cm2]2.8×10-20
量子效應,lpump / lse,[nm]0.959
熒光壽命,tem [ms]0.6

吸收和發射光譜

Yb-KGW激光晶體-吸收放射譜-南京光寶-CRYLINK

參考文獻

[1]? Major A ,? Cisek R ,? Greenhalgh C , et al. A diode-pumped high power extended cavity femtosecond Yb:KGW laser: From development to applications in nonlinear microscopy[C]// Photonics North 2006. 2006.
[2]? Zhao H ,? Major A . Megawatt peak power level sub-100 fs Yb:KGW oscillators[J]. Optics Express, 2014, 22(25):30425-31.
[3]? Paunescu G ,? Hein J ,? Sauerbrey R . 100-fs diode-pumped Yb:KGW mode-locked laser[J]. Applied Physics B, 2004, 79(5):555-558.
[4]? Kuleshov N V ,? Lagatsky A A ,? Shcherbitsky V G , et al. CW laser performance of Yb and Er,Yb doped tungstates[J]. Applied Physics B, 1997, 64(4):409-413.
[5]? Holtom G R . Mode-locked Yb:KGW laser longitudinally pumped by polarization-coupled diode bars[J]. Optics Letters, 2006, 31(18):2719-21.
[6]? Kuleshov N V ,? Lagatsky A A ,? Podlipensky A V , et al. Pulsed laser operation of Y b-dope d KY(WO(4))(2) and KGd(WO(4))(2).[J]. Optics Letters, 1997, 22(17):1317-9.
[7]? Zhao H ,? Major A . Powerful 67 fs Kerr-lens mode-locked prismless Yb:KGW oscillator[J]. Optics Express, 2013, 21(26):31846-31851.
[8]? Pekarek S ,? Fiebig C ,? Stumpf M C , et al. Diode-pumped gigahertz femtosecond Yb:KGW laser with a peak power of 3.9 kW[J]. Optics Express, 2010, 18(16):16320-16326.
[9]? Hellstroem J E ,? Bjurshagen S ,? Pasiskevicius V , et al. Efficient Yb:KGW lasers end-pumped by high-power diode bars[J]. Applied Physics B, 2006, 83(2):235-239.
[10]? Major A , D Sandkuijl,? Barzda V . Efficient frequency doubling of a femtosecond Yb:KGW laser in a BiB3O6 crystal[J]. Optics Express, 2009, 17(14):12039-42.
[11] S Chénais,? Druon F ,? Balembois F , et al. Thermal lensing measurements in diode-pumped Yb-doped GdCOB, YCOB, YSO, YAG and KGW[J]. Optical Materials, 2003, 22(2):129-137.
[12]? Major A , D Sandkuijl,? Barzda V . A diode-pumped continuous-wave Yb:KGW laser with Ng-axis polarized output[J]. Laser Physics Letters, 2010, 6(11):779-781.
[13]? Hellstrm J E ,? Bjurshagen S ,? Pasiskevicius V . Laser performance and thermal lensing in high-power diode-pumped Yb:KGW with athermal orientation[J]. Applied Physics B, 2006, 83(1):55-59.
[14]? Akbari R ,? Zhao H ,? Fedorova K A , et al. Quantum-Dot Saturable Absorber and Kerr Lens Mode-Locked Yb:KGW Laser with >300 kW of Peak Power[J]. Optics Letters, 2016, 41(16).
[15]? Russbueldt P ,? Mans T ,? Weitenberg J , et al. Compact diode-pumped 1.1 kW Yb:YAG Innoslab femtosecond amplifier[J]. Optics Letters, 2010, 35(24):4169-71.
[16]? Sandkuijl D ,? Cisek R ,? Major A , et al. Differential microscopy for fluorescence-detected nonlinear absorption linear anisotropy based on a staggered two-beam femtosecond Yb:KGW oscillator[J]. Biomedical Optics Express, 2010, 1(3):895-901.
[17]? Hellstrm J ,? Henricsson H ,? Pasiskevicius V , et al. Polarization-tunable Yb:KGW laser based on internal conical refraction[J]. Optics Letters, 2007, 32(19):2783-2785.
[18]? Joel A , Berger,? Michael J , et al. High-power, femtosecond, thermal-lens-shaped Yb:KGW oscillator.[J]. Optics express, 2008.
[19]? Major A ,? Cisek R ,? Barzda V . Development of diode-pumped high average power continuous-wave and ultrashort pulse Yb:KGW lasers for nonlinear microscopy[C]// Commercial and Biomedical Applications of Ultrafast Lasers VI. International Society for Optics and Photonics, 2006.
[20] Alexander, Klenner, Matthias, et al. A gigahertz multimode-diode-pumped Yb:KGW enables a strong frequency comb offset beat signal[J]. Optics Express, 2013.
[21]? Erhard S ,? Gao J ,? Giesen A , et al. High power Yb:KGW and Yb:KYW thin disk laser operation[C]// Conference on Lasers & Electro-optics. IEEE, 2001.
[22]? Zhao H ,? Major A . Orthogonally polarized dual-wavelength Yb:KGW laser induced by thermal lensing[J]. Applied Physics B, 2016, 122(6):1-6.
[23]? Akbari R ,? Zhao H ,? Major A . High-power continuous-wave dual-wavelength operation of a diode-pumped Yb:KGW laser[J]. Optics Letters, 2016, 41(7):1601.
[24] T Bal?iūnas, OD Mücke, P Mi?eikis, et al. Carrier envelope phase stabilization of a Yb:KGW laser amplifier[J]. Optics Letters, 2011, 36(16):3242.
[25]? Lagatsky A A ,? Abdolvand A ,? Kuleshov N V . Passive Q switching and self-frequency Raman conversion in a diode-pumped Yb:KGd(WO4)2 laser[J]. Optics Letters, 2000, 25(9):616-8.
[26]? Molis G ,? Adomavicius R ,? Krotkus A , et al. Terahertz time-domain spectroscopy system based on femtosecond Yb:KGW laser[J]. Electronics Letters, 2007, 43(3):190-191.
[27]? Hoos F ,? Li S ,? Meyrath T P , et al. Thermal lensing in an end-pumped Yb : KGW slab laser with high power single emitter diodes[J]. Optics Express, 2008, 16(9):6041-6049.
[28]? Kisel V E ,? Rudenkov A S ,? Pavlyuk A A , et al. High-power, efficient, semiconductor saturable absorber mode-locked Yb:KGW bulk laser[J]. Optics Letters, 2015, 40(12):2707-10.

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